Advanced Biofuels of the Future: Atom-Economical or Energy-Economical?
نویسندگان
چکیده
منابع مشابه
Chlorine, an atom economical auxiliary for asymmetric aldol reactions.
An auxiliary strategy has been developed for asymmetric reactions of aldehydes in which the auxiliary itself is not chiral, but a single chlorine atom introduced via organocatalytic α-chlorination. The stereodirecting influence of the chlorine atom is then exploited prior to its removal by radical reduction. This strategy is demonstrated in the synthesis of several aldols (92-99% ee) and the na...
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ژورنال
عنوان ژورنال: Joule
سال: 2018
ISSN: 2542-4351
DOI: 10.1016/j.joule.2018.09.007